Heteroleptic copper complexes with nitrogen and phosphorus ligands in photocatalysis: Overview and perspectives
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چکیده
منابع مشابه
Syntheses, Characterization and Solvatochromism Study of Heteroleptic Chelated Copper(II) Complexes Containing N,N- dibezyl Substituted Ethylenediamine and Acetylacetonate Ligands
A series of new heteroleptic chelated copper(II) complexes that encompass N,N-dibezyl substituted derivative of ethylenediamine (X-diamine) and acetylacetonate (acac) were prepared. The IR and electronic absorption spectra and the molar conductivity of the complexes are presented and discussed. The molar conductivity values of the complexes in different solvents reveals a predominance of elec...
متن کاملSolvatochromic Properties of Heteroleptic Copper(II) Complexes Containing N,N,N',N'-Tetramethylethylenediamine and 2-Aacetylcyclopentanone Ligands
Three new heteroleptic copper(II) complexes, [(tmen)Cu(dike)H2O]X where tmen = N,N,N',N'-tetramethylethylenediamine, dike = 2-acetylcyclopentanone anion and X= ClO4- (1), Cl- (2) and Br- (3) are prepared and characterized by elemental analyses, molar conductance measurements and IR and UV-Vis spectroscopy techniques. The complex 1 is fairly soluble in various organic solvents and demonstrates d...
متن کاملElectrophosphorescent homo- and heteroleptic copper(I) complexes prepared from various bis-phosphine ligands.
Homo- and heteroleptic copper(I) complexes obtained from various chelating bis-phosphine ligands and Cu(CH3CN)4BF4 have been used for the preparation of light emitting devices.
متن کاملsyntheses, characterization and solvatochromism study of heteroleptic chelated copper(ii) complexes containing n,n- dibezyl substituted ethylenediamine and acetylacetonate ligands
a series of new heteroleptic chelated copper(ii) complexes that encompass n,n-dibezyl substituted derivative of ethylenediamine (x-diamine) and acetylacetonate (acac) were prepared. the ir and electronic absorption spectra and the molar conductivity of the complexes are presented and discussed. the molar conductivity values of the complexes in different solvents reveals a predominance of elec...
متن کاملCopper complexes of nitrogen-anchored tripodal N-heterocyclic carbene ligands.
Incorporation of a nitrogen functionality into a tripodal N-heterocyclic carbene ligand system affords the first N-anchored tetradentate tris-carbene ligands TIMEN(R) (R = Me (5a), t-Bu (5b), Bz (5c)). Treatment of the methyl derivatized [H(3)TIMEN(Me)](PF(6))(3) imidazolium salt (H(3)5a) with silver oxide yields the silver complex [(TIMEN(Me))(2)Ag(3)](PF(6))(3) (9), which, in a ligand transfe...
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ژورنال
عنوان ژورنال: Chem Catalysis
سال: 2021
ISSN: 2667-1093
DOI: 10.1016/j.checat.2021.05.005